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Download Pavel Corut Carte. Search Pavel Corut Carte by category or author name.The present invention relates to an improved bipolar plate for use in an electrolytic cell to produce a metal from the halide of an alkali metal such as sodium, potassium or lithium.
Sodium and potassium are stored as ferrocyanides or ferricyanides in large amounts and are used as a source of sodium and potassium in nuclear technology, ceramics, glass, glass-ceramics, and in metallurgy. The consumption of such salt in electric power generation and industry is considerable.
The sources of sodium and potassium are lake salts or sea salts. Smaller amounts of sodium and potassium are found in the form of carbonate or nitrate. The salts are either liquid or solid depending on their content of halide and on the concentration of water. They may be in the form of multivalent salts such as the chlorides or bromides. The electrolysis of these salts in an electrolytic cell leads to the generation of sodium and potassium vapors which should not be released into the atmosphere. The electrolysis of these salts is conducted in a cell using a porous cathode, a platinum metal anode and a non-porous, liquid, polymeric ceramic ion-exchange membrane. The cell also contains a thin layer of the electrolyte in contact with the anode.
It is the object of the present invention to provide a bipolar plate for use in an electrolytic cell which helps to prevent sodium and potassium vapors from being released from the anode side of the electrolytic cell. In accordance with the invention, the bipolar plate is formed of a non-porous, liquid polymeric material which is resistant to attack by both the halide ions and the alkali ions in the electrolyte and is able to carry a high electrical current during operation of the cell.
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